MIT Team Makes a Case For Direct Carbon Capture From Seawater, Not Air
It turns out there’s another option: seawater. As atmospheric carbon concentrations rise, carbon dioxide begins to dissolve into seawater. The ocean currently soaks up some 30-40% of all humanity’s annual carbon emissions, and maintains a constant free exchange with the air. Suck the carbon out of the seawater, and it’ll suck more out of the air to re-balance the concentrations. Best of all, the concentration of carbon dioxide in seawater is more than 100 times greater than in air. Previous research teams have managed to release CO2 from seawater and capture it, but their methods have required expensive membranes and a constant supply of chemicals to keep the reactions going. MIT’s team, on the other hand, has announced the successful testing of a system that uses neither, and requires vastly less energy than air capture methods.
In the new system, seawater is passed through two chambers. The first uses reactive electrodes to release protons into the seawater, which acidifies the water, turning dissolved inorganic bicarbonates into carbon dioxide gas, which bubbles out and is collected using a vacuum. Then the water’s pushed through to a second set of cells with a reversed voltage, calling those protons back in and turning the acidic water back to alkaline before releasing it back into the sea. Periodically, when the active electrode is depleted of protons, the polarity of the voltage is reversed, and the same reaction continues with water flowing in the opposite direction. In a new study published in the peer-reviewed journal Energy & Environmental Science, the team says its technique requires an energy input of 122 kJ/mol, equating by our math to 0.77 mWh per ton. And the team is confident it can do even better: “Though our base energy consumption of 122 kJ/mol-CO2 is a record-low,” reads the study, “it may still be substantially decreased towards the thermodynamic limit of 32 kJ/mol-CO2.”
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